Wednesday, June 30, 2010

OK.....A FEW MORE QUESTIONS I HAVE....






...........I think that reactions in the seawater are producing something like Lewisite.....why ?

      Lewisite is an organoarsenic compound, specifically an arsine. It was once manufactured in the U.S. and Japan as a chemical weapon, acting as a vesicant (blister agent) and lung irritant. Although chlorovinyl dichloroarsine is colorless and odorless, the impure samples in lewisite are yellow or brown liquid


   Organoarsenic chemistry is the chemistry of compounds containing a chemical bond between arsenic and carbon. A few organoarsenic compounds, also called "organoarsenicals," are produced industrially with uses as insecticides, herbicides, and fungicides. In general these applications are declining in step with growing concerns about their impact on the environment and human health. The parent compound is arsine. Despite their toxicity, organoarsenic biomolecules are well known.


   A biomolecule is any organic molecule that is produced by a living organism, including large polymeric molecules such as proteins, polysaccharides, and nucleic acids as well as small molecules such as primary metabolites, secondary metabolites, and natural products. A more general name for this class of molecules is a biogenic substance


     As organic molecules, biomolecules consist primarily of carbon and hydrogen, nitrogen, and oxygen, and, to a smaller extent, phosphorus and sulfur.



   A biogenic substance is a substance produced by life processes. It may be either constituents, or secretions, of plants or animals. A more specific name for these substances is biomolecules
Coal and oil are possible examples of constituents which may have undergone changes over geologic time periods.


..........given the electrochemical potential of the incredible salinity of the lower depths of the G.o.M.....approaching 35% in most deep water areas...and the fact that it is the most prone area on the planet to get lightning over the water due to high salinity.....,.......and a few other factors......like equatorial  proximity to the Sun meaning higher counts of solar electron particle bombardment rates....and the recent storms exceeding the max MeV electron ratings of 1000 p.f.u.'s..( P.article F.lux U.nit )..they have gone over 20000pfu's this month  ......I think that Mustard gas is being produced...a natural chemical reaction in the seawater with naturally produced sulfur...........but also exacerbated by relativistic effects....ie: 2MeV electrons.......what's happening in the Gulf...........is an event formed by the convergence of many factors......anyway.....it's all explained underneath.


......for those of you in the petroleum industry or any other related industry, or US government organization that are reading this....read below.....I know you are lying....


 .....For everybody else reading this,..if you have noticed that birds are disappearing, more bugs are around....less birds singing in the morning and night....or no birds singing at all........burning in your nose after it rains.....or any other strange things..the smell of onions or garlic.......leave a comment at the bottom of this post.

                 Link to the CDC page about mustard gas/sulfur mustard------>   LINK


   Like I have always said. .....The truth is stranger than fiction......that is why secrets remain secrets......nobody would believe them anyway....
                                                 
                                                                                          - Isaac

--------------------------------------------------

” So far, 400 people have sought medical care for upper or lower respiratory problems, headaches, nausea, and eye irritation after trips to Escambia County beaches, Lanza said.

   By 10 a.m. on Friday, the double red flags prohibiting beachgoers from the water were replaced with yellow flags.“We’re flying the yellow flags. And that means you need to be careful where you step,” Lee said. “Just be careful and have a good time.”

The following was spotted on the Yahoo Wall street investors board today..(2/27/2010)

” This is terrible news for sure. And it’s already started. It was on our local news 3 station showing the crops and birds dying.

See my other post for the link or just google toxic rain killing crops. I’ve never seen dead birds just hanging out of their bird houses like this before. No signs of oil on them..just DEAD! ”

—Portsmouth, VA

” We are having an unprecedented incidence of recently dead birds here. Fisherman say they have never seen this before. The numbers must be large because they sink pretty quickly so you only see the most recent still floating. We are 1200 miles s.e. of Miami. ”

—Antigua

http://blog.alexanderhiggins.com/2010/06/28/federal-advice-pensacola-beach-opens-400-people-sick/comment-page-1/#comment-2213



  There are many more reports , all the same, I will place them at the bottom of this post.one-by-one.

 ....Hydrogen sulfide., ....since it is being obviously produced in some quantity by microbes..and also when seawater reacts with natural sulfates in sub-floor rock formations.....…..Sour High-E oil…is high in sulfur..


....The sulfur mustards, of which mustard gas (1,5-dichloro-3-thiapentane) is a member, are a class of related cytotoxic, vesicant chemical warfare agents with the ability to form large blisters on exposed skin. Pure sulfur mustards are colorless, viscous liquids at room temperature. However, when used in impure form, such as warfare agents, they are usually yellow-brown in color and have an odor resembling mustard plants, garlic or horseradish, hence the name. Mustard gas was originally assigned the name LOST, after Lommel and Steinkopf, who first proposed the military use of sulfur mustard to the German Imperial General Staff.
Mustard agents are regulated under the 1993 Chemical Weapons Convention (CWC).

   Three classes of chemicals are monitored under this Convention, with sulfur and nitrogen mustard grouped in Schedule 1, as substances with no use other than chemical warfare. Mustard agents can be deployed on the battlefield via spraying from aircraft, or more typically by means of air-dropped bombs or artillery shells.

...Sulfur mustard is the organic compound described with the formula (ClCH2CH2)2S. In the Depretz method, mustard gas is synthesized by treating sulfur dichloride with ethylene.:
SCl2 + 2 C2H4 → (ClCH2CH2)2S
....Sulfur dichloride is the chemical compound with the formula SCl2. This cherry-red liquid is the simplest sulfur chloride and one of the most common. It is used as a precursor to organosulfur compounds.

....Chlorination of sulfur SCl2 is produced by the chlorination of either elemental sulfur or disulfur dichloride.  

....Sulfer is found in great quantities in HIGH-E sour crude, like what is in the G.o.M. area...

  Sour crude oil is crude oil containing the impurity sulfur. It is common to find crude oil containing some impurities. When the total sulfur level in the oil is > 0.5 % the oil is called "sour".



   The impurities need to be removed before this lower quality crude can be refined into gasoline, thereby increasing the cost of processing. This results in a higher-priced gasoline than that made from sweet crude oil. Thus sour crude is usually processed into heavy oil such as diesel and fuel oil rather than gasoline to reduce processing cost.

   The majority of the sulfur in crude oil occurs bonded to carbon atoms, with a small amount occurring as elemental sulfur in solution and as hydrogen sulfide gas. Sour oil can be toxic and corrosive, especially when the oil contains high levels of hydrogen sulfide. At low concentrations the oil has the smell of rotten eggs, but at high concentrations the inhalation of hydrogen sulfide is instantly fatal. At higher concentrations, the hydrogen sulfide can damage the olfactory nerve, rendering the gas effectively odorless and undetectable, while paralyzing the respiratory system. If exposure is not fatal, its effects on the human body are similar to that of Gulf War Syndrome including chronic fatigue, headaches, dizziness, skin problems, memory problems, birth defects, and a host of breathing problems such as asthma. Sour crude oil needs to be stabilized by having hydrogen sulfide gas (H2S) removed from it before being transported by oil tankers for safety reasons.
Since sour crude is more common than sweet crude in the U.S. Gulf of Mexico,

Platts has come out in March 2009 with a new sour crude benchmark (crude oil) oil marker called "Americas Crude Marker (ACM)". Dubai Crude (and Oman Crude) both sour crude oils have been used as a benchmark (crude oil) oil marker for Middle East crude oils for some time.

    I'll leave the links in this for you.so you can see where the chemicals are coming from, and how they are being produced.


    Ethylene is oxidized to produce ethylene oxide, a key raw material in the production of surfactants and detergents by ethoxylation. Ethylene oxide also hydrolyzed to produce ethylene glycol, widely used as an automotive antifreeze as well as higher molecular weight glycols and glycol ethers.

   Ethylene is produced in the petrochemical industry by steam cracking......... Steam cracking is based on the natural cracking process that happens in reservoirs.......In this process, gaseous or light liquid hydrocarbons are heated to 750–950 °C, inducing numerous free radical reactions followed by immediate quench to stop these reactions. This process converts large hydrocarbons into smaller ones and introduces unsaturation. Ethylene is separated from the resulting complex mixture by repeated compression and distillation. In a related process used in oil refineries, high molecular weight hydrocarbons are cracked over zeolite catalysts. Heavier feedstocks, such as naphtha and gas oils require at least two "quench towers" downstream of the cracking furnaces to recirculate pyrolysis-derived gasoline and process water. 



....... Next, I'll quote this paper, published last year.

 

Natural gas at thermodynamic equilibrium Implications for the origin of natural gas.

Frank D Mango1 email, Daniel Jarvie2 email and Eleanor Herriman1 email
Petroleum Habitats, 806 Soboda Ct., Houston, Texas 77079, USA
Worldwide Geochemistry, 218 Higgins Street, Humble, Texas 77338, USA

Received: 24 February 2009
Accepted: 16 June 2009
Published: 16 June 2009


   The hydrocarbons in natural gas are believed to come from two sources, one biological ('biogenic gas'), and the other from thermal cracking, 'primary thermal gas' from kerogen cracking and 'secondary thermal gas' from oil cracking . Although there is general agreement on the source of biogenic gas, disagreement persists over the origin of thermal gas. One point of controversy is that thermal cracking does not produce a gas resembling natural gas. Oil and kerogen pyrolysis typically give between 10 and 60% wt methane (C1–C4) while natural gas contains between 60 and 95+% methane None of the explanations that have been offered to explain this are satisfactory. Catalysis by reduced transition metals can, in theory, explain high-methane in natural gas , and this hypothesis is supported by experimental results. Crude oils and n-alkanes decomposed over reduced nickel and cobalt oxides produce gas resembling natural gas in molecular and isotopic compositions . There is, however, no evidence of metal activity in sedimentary rocks and therefore no compelling reason to question thermal cracking theory. Moreover, recent hydrous pyrolysis experiments with metal-rich Permian Kupferschiefer shale showed little evidence of catalytic activity, seemingly dismissing the possibility of a catalytic path to natural gas .

   Gas metathesis without the aid of a catalytic agent is highly unlikely. Hydrocarbon cracking generates methane, ethane, and propane removed from thermodynamic equilibrium and their extraordinary thermal stabilities preclude equilibrium over geologic time. Thus natural gas at metathetic equilibrium (3) would implicate catalytic assistance.

    This changed with the recent disclosure of natural catalytic activity in marine shales at temperatures 300° below thermal cracking temperatures . Shales generated gas under anoxic gas flow at 50°C, nearly five times more gas than the same shale would generate at 350°C through thermal cracking. Although there was only indirect evidence for transition metals as the active catalysts, it nevertheless established natural catalytic activity in source rocks believed to be major sources of natural gas. There are, therefore, two possible paths to natural gas, a thermogenic path operating almost exclusively at high temperatures, and a catalytic path operating at much lower temperatures. The latter redefines the time-temperature dimensions of gas habitats opening the possibility of gas generation at subsurface temperatures previously thought impossible.


http://www.geochemicaltransactions.com/content/10/1/6


.......ethane is also a product of UV photolysis of methane........

   Ultraviolet (UV), X-Ray and shorter wavelengths of solar radiation are ionizing, since photons at these frequencies contain sufficient energy to dislodge an electron from a neutral gas atom or molecule upon absorption. In this process the light electron obtains a high velocity so that the temperature of the created electronic gas is much higher (of the order of thousand K) than the one of ions and neutrals. The reverse process to Ionization is recombination, in which a free electron is "captured" by a positive ion, occurs spontaneously. This causes the emission of a photon carrying away the energy produced upon recombination. As gas density increases at lower altitudes, the recombination process prevails, since the gas molecules and ions are closer together. The balance between these two processes determines the quantity of ionization present.


http://en.wikipedia.org/wiki/Ionosphere


Just one recent storm....we've been getting blasted by many different types for a few years now, too. Heat-waves....my *ss.

Space Weather Message Code: ALTEF3
Serial Number: 1677
Issue Time: 2010 Jun 02 0512 UTC

CONTINUED ALERT: Electron 2MeV Integral Flux exceeded 1000pfu
Continuation of Serial Number: 1676
Begin Time: 2010 May 30 1015 UTC
Yesterday Maximum 2MeV Flux: 20865 pfu


   The π-bond in the ethylene molecule is responsible for its useful reactivity. The double bond is a region of high electron density, thus it is susceptible to attack by electrophiles. Many reactions of ethylene are catalyzed by transition metals, which bind transiently to the ethylene using both the π and π* orbitals.


   In chemistry, an electrophile (literally electron-lover) is a reagent attracted to electrons that participates in a chemical reaction by accepting an electron pair in order to bond to a nucleophile. Because electrophiles accept electrons, they are Lewis acids (see acid-base reaction theories). Most electrophiles are positively charged, have an atom which carries a partial positive charge, or have an atom which does not have an octet of electrons.


  Not directed at my readers....well, ok...one or two........you know who you are
........now tell me I'm a loon......*ssh*le....(see below post)


........... Next, how natural chlorine is formed in seawater...


   Chlorine (from Greek: χλωρóς (khlôros), 'pale green') is the chemical element with atomic number 17 and symbol Cl. It is a halogen, found in the periodic table in group 17 (formerly VII, VIIa, or VIIb). As the chloride ion, which is part of common salt and other compounds, it is abundant in nature and necessary to most forms of life, including humans. In its elemental form (Cl2 or "dichlorine") under standard conditions, chlorine is a powerful oxidant and is used in bleaching and disinfectants, as well as an essential reagent in the chemical industry. As a common disinfectant, chlorine compounds are used in swimming pools to keep them clean and sanitary. In the upper atmosphere, chlorine-containing molecules such as chlorofluorocarbons have been implicated in the destruction of the ozone layer.
....Chlorine is a member of the salt-forming halogen series and is extracted from chlorides through oxidation often by electrolysis. With metals, it forms salts called chlorides. As the chloride ion, Cl, it is also the most abundant dissolved ion in ocean water....

....Owing to their high reactivity, the halogens are found in the environment only in compounds or as ions. Halide ions and oxoanions such as iodate (IO3) can be found in many minerals and in seawater.

    Halogens are highly reactive, and as such can be harmful or lethal to biological organisms in sufficient quantities. This high reactivity is due to the atoms being highly electronegative due to their high effective nuclear charge. They can gain an electron by reacting with atoms of other elements.

...Look at the lightning strike charts in the post below this one.....the G.o.M. in particular.

    The halogens react with each other to form interhalogen compounds. Diatomic interhalogen compounds such as BrF, ICl, and ClF bear resemblance to the pure halogens in some respects. The properties and behaviour of a diatomic interhalogen compound tend to be intermediate between those of its parent halogens. Some properties, however, are found in neither parent halogen. For example, Cl2 and I2 are soluble in CCl4, but ICl is not since it is a polar molecule due to the relatively large electronegativity difference between I and Cl.

    Many synthetic organic compounds such as plastic polymers, and a few natural ones, contain halogen atoms; these are known as halogenated compounds or organic halides. Chlorine is by far the most abundant of the halogens, and the only one needed in relatively large amounts (as chloride ions) by humans.

   In drug discovery, the incorporation of halogen atoms into a lead drug candidate results in analogues that are usually more lipophilic and less water soluble. Consequently, halogen atoms are used to improve penetration through lipid membranes and tissues. Consequently, there is a tendency for some halogenated drugs to accumulate in adipose tissue.

    The chemical reactivity of halogen atoms depends on both their point of attachment to the lead and the nature of the halogen. Aromatic halogen groups are far less reactive than aliphatic halogen groups, which can exhibit considerable chemical reactivity. For aliphatic carbon-halogen bonds the C-F bond is the strongest and usually less chemically reactive than aliphatic C-H bonds. The other aliphatic-halogen bonds are weaker, their reactivity increasing down the periodic table. They are usually more chemically reactive than aliphatic C-H bonds. Consequently, the most common halogen substitutions are the less reactive aromatic fluorine and chlorine groups.

From Wikipedia…under the definition of sulfur mustard.

” Mustard gas has extremely powerful vesicant effects on its victims. Additionally, it is strongly mutagenic and carcinogenic, due to its alkylating properties. It is also lipophilic. Because people exposed to mustard gas rarely suffer immediate symptoms, and mustard-contaminated areas may appear completely normal, victims can unknowingly receive high dosages ”

” Mustard gas vapour easily penetrates clothing fabrics such as wool or cotton, so it is not only the exposed skin of victims which gets burned. If the victim’s eyes were exposed then they become sore, starting with conjunctivitis, after which the eyelids swell, resulting in temporary blindness. ”

http://en.wikipedia.org/wiki/Sulfur_mustard#Physiological_effects

Again…from the article on Alex Higgin's blog

” So far, 400 people have sought medical care for upper or lower respiratory problems, headaches, nausea, and eye irritation after trips to Escambia County beaches, Lanza said.”



              They are lying......

There are large amounts of hydrogen sulfide present in the Gulf area.


A closer look at sulfur and where it's coming from.

    A pale yellow nonmetallic element occurring widely in nature in several free and combined allotropic forms. It is used in black gunpowder, rubber vulcanization, the manufacture of insecticides and pharmaceuticals, and in the preparation of sulfur compounds such as hydrogen sulfide and sulfuric acid. Atomic number 16; atomic weight 32.066; melting point (rhombic) 112.8°C, (monoclinic) 119.0°C; boiling point 444.6°C; specific gravity (rhombic) 2.07, (monoclinic) 1.957; valence 2, 4, 6.

    Nonmetallic chemical element, chemical symbol S, atomic number 16. It is very reactive but occurs native in deposits, as well as combined in various ores (e.g., pyrite, galena, cinnabar); in coal, petroleum, and natural gas; and in the water in sulfur springs. Sulfur is the third most abundant constituent of minerals and one of the four most important basic chemical commodities. Pure sulfur, a tasteless, odourless, brittle yellow solid, occurs in several crystalline and amorphous allotropes, including brimstone and flowers of sulfur. It combines, with valence 2, 4, or 6, with nearly all other elements. Its most familiar compound is hydrogen sulfide, a poisonous gas that smells like rotten eggs. All metals except gold and platinum form sulfides, and many ores are sulfides. The oxides are sulfur dioxide and sulfur trioxide, which when dissolved in water make sulfurous acid and sulfuric acid, respectively. Several sulfur compounds with halogen elements are industrially important. Sodium sulfite (Na2SO3) is a reducing agent used to pulp paper and in photography. Organic compounds with sulfur include several amino acids, the sulfa drugs, and many insecticides, solvents, and substances used in making rubber and rayon.
...........I think that  reactions in the seawater are producing something like Lewisite.....why ?

 ------------

From the NDRC..

" Have you had any reports that the oil is making people sick?

We have been hearing some reports from people along the coast who are noticing the smell of oil. Some people have been complaining of headaches, nausea, coughing and throat irritation. We are collecting reports of health problems.  "

http://www.simplesteps.org/questions/how-will-gulf-coast-oil-spill-affect-my-health

http://www.nrdc.org/about/default.asp

-----------------

By the CNN Wire Staff
May 28, 2010 8:43 a.m. EDT

"The heat and humidity in Louisiana can be challenging," Coast Guard Rear Adm. Mary Landry told reporters Thursday afternoon.

She said the workers were treated for several symptoms, including headaches, nausea, vomiting and shortness of breath. Safety officials from the Coast Guard, BP and the federal Occupational Safety and Health Administration had responded to the incident, Landry.

"Basically, these folks all had the proper personal protective equipment on, and they all received the required training," she said. "Fortunately, everyone is fine."

http://www.cnn.com/2010/US/05/27/gulf.oil.spill.sickness/index.html-------------

/May-27-2010_12-37-am/

 by (AP) COVINGTON, Louisiana
Published: Wed, May 26, 2010 - 11:26 pm CST

Covington, Louisiana - The U.S. Coast Guard has pulled commercial fishing boats from Gulf of Mexico oil cleanup efforts in Breton Sound off the Louisiana coast after several people became ill.

The Coast Guard says crew members on three vessels reported nausea, dizziness, headaches and chest pains Wednesday afternoon. Four people were hospitalized, including one who was flown to a hospital.

The Coast Guard told all 125 commercial vessels that were helping clean up spilled oil to return to shore. Medical workers evaluated the crew members as a precaution.

Breton Sound is about 30 miles (50 kilometers) southeast of New Orleans.



http://www.wkrg.com/gulf_oil_spill/article/boats-pulled-from-oil-cleanup-after-crews-get-sick/890572-------------------

 by Associated Press

Published: Thu, June 03, 2010 - 11:35 am CST

Associated Press - For days now, Dr. Damon Dietrich has seen patients come through his emergency room at West Jefferson Medical Center with similar symptoms: respiratory problems, headaches and nausea.

In the past week, 11 workers who have been out on the water cleaning up oil from BP's blown-out well have been treated for what Dietrich calls "a pattern of symptoms" that could have been caused by the burning of crude oil, noxious fumes from the oil or the dispersants dumped in the Gulf to break it up. All workers were treated and released.

"One person comes in, it could be multiple things," he said. "Eleven people come in with these symptoms, it makes it incredibly suspicious."

6/30/2010, 10:35 AM-EST    - Isaac

In the meantime....here's some recent screen caps for you all.....so you can see a little of who's been reading along with you........







  
                                                                                                                        I accidentally deleted the Department of Homeland Security screen cap.....slaps forehead..                  s'okay.....I have a feeling they'll be back..                                                   This how to tell who is reading info from a server on your computer, ...or, who's connected to you.   Type CMD, then netstat.    simple.                                                                                     
                                                                                          Here's just one way you can trace the location.                                                   
                                                                                                          Hello to my friends down under ..                                                      Anyways, I'll just say this.....when I randomly run a netstat, and find certain oil company or military/US Gov. computers connected to my computer.......and I find a telnet executable, that I cannot gain control over......stored in my temporary internet files....with remote log-on permissions granted for up to 10 people...." Microsoft Outlook Exploit ".    I know what you are doing....... I have since it was installed....I am curious tho',... how you forced it over wireless..










( EDIT )   Holy shit....that was fast...........3:38 PM EST



Here's a few packet trace routes...









                                                You are watching me.....
                                 ..I am watching you...
                                             ... for the first time in a while  ....
                                ...the world is watching too..


http://en.wikipedia.org/wiki/Sour_crude_oil

1 comment:

Isaacnd said...

I see....well, keep your head down and keep working then, nobody likes a complainer. BTW, I have no IP addresses from Russia in my IP logs.

Have fun with your fantasy.

Isaac.